Wednesday, 26 November 2014

Chapter 1&2 test Class XII

Time:  1 hr.                                                                                        Max. Marks: 30

Q1. What is the value of Van’t Hoff factor for: (i) Al2(SO4)3      
(ii) Dimerization of benzoic acid?                                     (1)
Q2. Which magnetic substances can behave as permanent magnets and why?                                                                   (1)
Q3. Which point defect lowers the density of a crystal?                                                                                                                  (1)
Q4. Which colligative property is preferred for the calculation of molecular mass of macromolecules?                     (1)
Q5. Which type of semi-conductor is formed when: (i) Si is doped with P, (ii) Si is doped with In.                                                (1)
Q6. Calculate the fraction of M2+ and M3+ ions present in M0.98O1.00 .                                                                                        (2)
Q7. Determine amount of CaCl2 dissolved in 2.5 L of water such that its osmotic pressure is 0.75 atm at 270C, assuming that it is completely dissociated.                                                                                                                                         (2)
Q8. Why LiCl acquires pink colour when heated in Li vapours?                                                                                                     (2)
Q9. (i) Atoms of element B form hcp lattice and those of the element A occupy 2/3 rd of tetrahedral voids. What is the formula of the compound formed by the elements A and B?                                                                                                      (2)
(ii) State the condition resulting in reverse osmosis.
Q10. Gold (atomic mass = 197 u, atomic radius = 0.144nm) crystallises in fcc lattice. Determine the density of the gold.                                                                                                                               (2)
Q11. Determine the molarity of an antifreeze solution containing 250g water mixed with 222g ethylene glycol (C2H6O2). The density of this solution is 1.07g/mL.                                                                                                                         (2)
Q12. Derive the relationship between relative lowering of vapour pressure and molecular mass of solute.            (2)
Q13. Vapour pressure of chloroform (CHCl3 ) and dichloromethane (CH2Cl2) at 298 K are 200 mm Hg and 415 mm Hg respectively.(i) Calculate the vapour pressure of the solution prepared by mixing 25.5 g of CHCl3 and 40 g of CH2Cl2 at 298 K and,(ii) mole fraction of each component in vapour phase.                                                                                                          (3)
Q14. Write main difference between the following with an example of each:                        
(i) Ideal and Non-ideal solution
(ii) Schottky and Frenkel Defect.                                                                                                                     (3)
Q15. a) Draw the graph showing depression of the freezing point of a solvent in a solution. Also, define Cryoscopic constant.

b) Two elements A and B form compounds having formula AB2 and AB4. When dissolved in 20g of benzene, 1g of  AB2 lowers the freezing point by 2.3K whereas 1g of AB4 lowers the freezing point by 1.3K. The molal depression constant for benzene is 5.1 KKg/mol. Calculate atomic messes of A and B.                                                                                                      (5)   

Previous Year Paper Class XII

Class – XII
Subject – Chemistry
Time:3hrs                                                                                                                                               MM:70
General instructions:
All questions are compulsory.
Questions number 1 to 8 are very short –answer questions, carrying 1 mark each.
Questions number 9 to18 are short –answer questions, carrying 2 marks each.
Questions number19 to27 are short –answer questions, carrying 3 marks each.
Questions number28 to30 are long-answer questions of 5 marks each.
Q1. Define F-centres.
Q2. Why is enthalpy of chemisorption higher than that of physisorption?
Q3. An ore sample of PbS is contaminated with ZnS. Name one chemical which can be used to concentrate galena selectively by froth floatation method.
Q4. A and B liquids on mixing produce a warm solution. Which type deviation from  Raoult’s law is there?
Q5. Give the IUPAC name of the following compound: CH3COCH2CH2CHO. 

Q6. Except for vitamin B12, all other vitamins of group B, should be taken regularly in diet. Why?
Q7. The decomposition of ammonia gas on platinum surface has a rate constant k = 2.5 X 10-4 mol/L/s. What is the order of a reaction?
Q8. What is the molecularity of the reaction: Cl → ½ Cl2?

Q9. How does molar conductance vary with concentration in strong and weak electrolytes? Explain with the help of graph.

Q10. An element E crystallises in bcc structure. If the edge length of the cell is 1.469 X 10-10 m and the density is 19.3 g/cm3, calculate the atomic mass of this element.

Q11. Define emulsions. Classify them giving an example of each.

Q12. Classify colloids on the basis of interaction between dispersed phase and dispersion medium. Write two differences between them.

Q13. (a) What is the covalence of nitrogen in N2O5?
(b) Explain why both N and Bi do not form pentahalides.
Q14. (a)Write the reaction involved in the preparation of tert-butyl ethyl ether by Williamson’s synthesis.
(b) Give reason: Propanol has higher boiling point than propane.
Q15. (a) How can you convert an amide into an amine having one carbon less than the starting compound?
(b) Give the IUPAC name and structure of the amine obtained by the above method if the amide is 3-Chlorobutanamide.
Q16. (a) Why does chlorine water lose its yellow colour on standing?
(b) What happens when Cl2 reacts with cold and dilute solution of sodium hydroxide? Write the reaction involved.

Q17. How would you distinguish between 10, 20 and 30 amines by a chemical test. Write the reactions to justify your answer.
Q18. Give the mechanism for the preparation of ethanol from ethene by acidic hydration.
Q19. Geeta and her sister Reeta called refrigeration mechanic for the repair of their refrigerator which was not lowering the temperature and food particles were getting destroyed. The mechanic came told the sisters that it requires filling of the gas. “But where has the earlier gas gone”, asked the sisters. The mechanic told that gas leaked out perhaps due to the poor repairs done by the earlier mechanic. They knew the ill effects of Freon gas and told the mechanic to fill and seal the gas carefully.
(a) What are the ill effects of Freon as discussed by Geeta and Reeta?
(b) How do you evaluate the consciousness of the sisters towards the environment?    

Q20. The decomposition of N2O5 (g) is a first order reaction with a rate constant of 5 X 10-4 s-1 at 45oC, i.e. 2 N2O5 (g) → 4 NO2 (g) + O2 (g). If initial concentration of N2O5 is 0.25M, calculate its concentration after 2 min. Also calculate half life for decomposition of N2O5 (g).
Q21. (a) Name the method used for refining of (i) nickel, (ii) zirconium.
(b) The extraction of Au by leaching with NaCN involves both oxidation and reduction. Justify giving equations.
                                    
Q22. Write down the equations of hydrolysis of XeF4 and XeF6. Which of these two reactions is a redox reaction?

Q23. (a) Explain bondings in metal carbonyls with orital diagram.
(b) Write the configuration of Ni in the complex [NiCl4]2- in terms of t2g and eg.

Q24.

Q25. i) Explain the mechanism of acid catalysed dehydration of ethanol forming ethene.
ii) Convert methanal to Ethanol by using Grignard’s reagent.
iii) Write the reaction between phenol and Br2 (aq).
Q26. Giving an example for each describe the following reaction:
i) HVZ reaction
ii) Reimer – Tiemer reaction
iii) Aldol condensation
Q27. i)Write the difference between antiseptic and disinfectants with one example in each.
ii) Give one example each of artificial sweetener and narrow spectrum antibiotic.
                Q28. (i) Account for the following : (i) Out of the ions Co2+, Sc3+ and Cr3+ ,which one would
 give coloured aqueous solutions  and why ?
(ii) Explain why chromium is a typical hard metal while mercury is a liquid.
(iii) Why do the transition elements form coloured compounds? Explain.
(iv)Why do the transition elements form interstitial compound?          
 (v) Complete the given reaction :                                                                                         
                  Cr2O72-  + H+  +Fe+2     →     ?
OR
 i) Transition metal compounds generally act as catalyst.(give reason)
ii) E0Mn3+/Mn2+ has higher positive value than E0 Cr3+/Cr2+.(Atomic number  Cr=24,Mn=25)
iii) How does KMnO4 can be prepared from pyrolusite ore?
iv) Why do the transition elements form coloured compounds? Explain.

Q29. (i) State Kohlrausch’s law.
(ii) Write down the reactions involved in the working of a H2––O2 fuel cell.
(iii) A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of     5.0 amperes for 20.0 minutes. What mass of Ni is deposited at the cathode? [ Atomic mass of Ni = 58.7u ]
OR
i)Write the anode and cathode reaction of lead storage battery.
ii) Define the molar conductivity .
iii) Calculate the equilibrium constant for the reaction
2Cr(s) +3Cd+2→2Cr+3(s) +3Cd
[ E0Cr3+/Cr   =  – 0.74 V and   E0Cd2+/Cd  =  + 0.40V ]

           
Q30. i) An organic compound with the molecular formula C9H10O forms 2,4-DNP derivative, reduces Tollen’s reagent and undergoes Cannizzaro reaction .On vigorous oxidation it gives 1,2-benzenedicarboxylic acid. Identify the organic compound.
ii) Arrange the following acid in increasing order of acidity:
CH3CH2CH(Br)COOH, CH3CHBrCH2COOH, (CH3)2CHCOOH, CH3CH2CH2COOH
(iii) Convert toluene  to benzaldehyde.
OR
Complete the following reaction.
i) Benzenamide to Chlorobenzene
ii)     Benzoyl chloride to benzaldehde                 
iii)Distinguish between the following by suitable chemical test and write chemical reaction:
a)Phenol and Benzoic acid
b)Benzylamine and Aniline.







IMPERFECTIONS IN SOLIDS

IMPERFECTIONS IN SOLIDS
IDEAL CRYSTAL : An ionic crystal has the same unit cell containing same lattice points throughout the whole of the crystal. It exists only at absolute zero (0K).
IMPERFECTIONS : It is the disorder from perfectly ordered state of constituents of crystals.
DEFECTS : are of two types –
1.) Point Defects – Defects at a particular lattice points.
2.) Line Defects – Defects in a complete row of a crystal lattice.
Three types of Point Defects : Stoichiometric defects, Non-Stoichiometric defects and Impurity defects
1.) STOICHIOMETRIC DEFECTS : The defects which donot effect the stoichiometric or formulae of a compound or a crystal. Stoichiometric  compounds are those in which no. of (+) and (-) ion are exactly in the ratio as indicated by their chemical formulae. It is of four types :
(a) Vacancy Defect : Some constituent particles are missing from their normal positions.
(b) Interstitial Defect : Some constituent particles are present in the vacant interstitial sites of a crystal lattice.
(c) Schottky Defect : It arises when no. of anions and cations are equally missing in a crystal lattice holes or vacancies. Density of a crystal gets decreased by it. Eg.- NaCl, CsCl, AgBr.  ( In NaCl, 10 schottly pairs per cc. are present ).
Causes : High coordination no. ; Cations and anions are of almost similar sizes.
(d) Frenkel Defect : When an ion (cation) is missing from its normal position and occupies an interstitial site b/w lattice points but the no. of anions and cations remain same, i.e., crystal is electrically neutral. It doesnot effect the density of a crystal. Eg.- AgCl, ZnS, AgBr.
Causes : Low CN; Anions are larger in size than cations.
2.) IMPURITY DEFECT : The cation gets replaced by another cation of similar size and high charge. Eg.- In Na  ions are replaced by Sr   ions, i.e., 2 Na  ions = 1 Sr   ions such that crystal remains electrically neutral. Also, doping of CdCl2 in AgCl.
3.) NON-STOICHIOMETIC DEFECT : The defect in which the ratio of (+) and (-) ions present in a compound becomes different from that required by chemical formulaes. It is of two types :
(a) Metal Excess Defect : (+) ions are in excess.  – Anion Vacancies ; - Excess cations
(i) Anion Vacancies : In this defect, anions may be missing from their lattice sites leaving holes in which electrons remain entrapped to maintain electrical neutrality. Eg. – When alkali metals are heated in the atmosphere of alkali metal vapors, anion vacancies are produced. Metal atoms get deposited on the surface of alkali metal halide crystal and halide ions diffuse out from the crystal to combine with metal atoms  leaving behind their electrons at anion vacancies known as F-centres. It causes violet colour in KCl, pink or lilac colour of LiCl, yellow colour in NaCl.
(ii) Excess Cations Occupying interstitial sites : In this defect, there are extra cations occupying interstitial sites and same no. of electrons in another interstitial sites to maintain electrical neutrality. Eg. – ZnO loses oxygen at high temperature and turns yellow in colour.
(b) Metal Deficient Defect : anions are in excess. – Cation Vacancies ; - Excess anions
(i) Cation Vacancies : Cations may be missing from their lattice sites. The extra (-) charge may be balanced by some nearby metal ion acquiring 2 (+) charges instead of 1. Eg.- In FeS, Fe   is absent or missing and 2Fe   ions are converted into Fe   to maintain electrical neutrality. As a result, crystal has metallic lusture nd iron pyrite is named as Fool’s Gold.
(ii) Extra Anions Occupying Interstitial Sites : In this case, extra anions occupy interstitial sites and extra (-) charge is balanced by extra charges on adjacent metal ions.

    




Value Based Questions in Chemistry



             Value Based Questions in Chemistry
1.  Manu went with his father to a Shopkeeper who showed them two types of batteries, one with lead plates and the other with cadmium plates. The battery with cadmium plates was more expensive than the lead battery. Manu’s father wanted to purchase lead battery as it was cheaper.
a.  As a student of chemistry, why would you suggest to Manu’s father to buy the expensive cadmium plate battery. Give two reasons.                                       (2)
b What are the values associated with the above decision?                        (1)
Ans:
a.  Cadmium plate battery though expensive is not as strong a pollutant as lead. Lead salts being insoluble in water if ingested into our system cannot be excreted out. Whereas Cd and Ni salts are water soluble, therefore get excreted and hence do not get biomagnified in the body.
b.  Keeping the environment safe from pollution due to lead.

2.  Kalavati wanted to give her baby a medicine for fever. She added boiled and cooled water as per the instruction, to the contents of the bottle, upto the mark. She shook the bottle. Then gave a spoonful of the medicine to the baby. As a student of chemistry answer the following questions:
a.  Why did she shake up the contents? What is the process called?                      (2)
b.  What is the value associated with selling medicine in this form?                         (1)
Ans:
a. She shook the contents of the bottle to bring the contents into the form of a sol. Absorption of medicine are easier in the colloidal form. This process of agitating a precipitate into colloidal sol is called as peptization.
b. When the medicine is sold in anhydrous form it has a higher shelf life and thus can be stored for a longer time. This is a way of being thrifty by not wasting the available resources.

3.  After entering a closed coal mine area, Ravi found difficulty in breathing, also felt nausea.
a.  What could be the reason for this?                                                                             (1)
b.  How could Ravi estimate the level of the pollutant?                                                (1)
c. As a citizen of the country what should be his course of action further?                         (1)
Ans:
a.  In coal mines due to lack of oxygen a small percentage of carbon monoxide is formed. This carbon monoxide being poisonous gives the symptoms.
b.  Ravi could estimate the level of CO using I2O5.
c.  Ravi should inform the concerned authority about the excess of CO in the coal mine.

4.  Sudanshu made a model of the unit cell of diamond. It resembled the unit cell of ZnS. If the unit cell of ZnS has 4 units of ZnS per unit cell. It has the same packing efficiency as ZnS. But diamond is the hardest known substance.

a.  What is the number of atoms of carbon per unit cell of diamond?           (1)
b.  Explain the reason for the above concept.                                    (1)
c What is the value that Sudanshu can derive from these facts?               (1)
Ans:
a)  The number of atoms of Carbon per unit cell is 8 in diamond.
b The C—C bond is very strong in diamond (due to small size of Carbon)
unlike the Zn—S bond in ZnS.
c)  Though from the same background ie with the same structure the property can be different, thus, with a little effort, we can do same things differently and bring about major changes.

5. Kartik went to a sugar producing factory. He noticed an alcohol producing unit associated with it. Generally alcohol is prepared industrially in places where sugar is extracted from sugarcane.
a.   As a student of chemistry, explain the reason for this.                  (2)
b What is the value derived from this fact?                                       (1)
Ans:
a. The molasses that are bi-products of sugar industry can be used in making alcohol.
b. Recycling of industrial waste keeps the environment clean.

6. Large amount of electricity is obtained in our country from burning of coal. The carbon in coal is lost as carbon dioxide, and water as water vapour. The substances left behind are minerals. These are known as fly ash. Fly ash is a major environmental hazard. Faseeh did a project on how to use this fly ash in building roads and in making roofing tiles. He was appreciated by the judges.  What was the value for which he was appreciated?
Ans: Recycling of industrial waste keeps the environment clean.                        (3)
           

7.   Ashraf is 50 years old and has diabetes. He uses saccharine as sweetening agent in tea and coffee and sugar free in sweets. Lakshmi too is diabetic. She controls her sugar level in diet by using less sugar and by exercising.
a. Who is able to handle diabetes more efficiently and why?                                    (1)
b. What value do you derive from this?                                                                       (1) c. What are the harmful effects of artificial sweeteners?                                       (1) Ans:
a. Lakshmi is able to handle diabetes better, because exercises activate the pancreases to produce insulin. Exercise keeps one fit and fine.
b. It is necessary to lead a disciplined life.
c. Researches have shown that the artificial sweeteners have harmful effect on the body because they are not excreted easily.

8. Almelu did not like the costlier brand of dish washer because she was not
satisfied by using less quantity of the dishwasher, so she bought the cheaper brand of dish washer and used large amounts of it.
a. As a student of chemistry what would you advise Almelu to use?                               (1)
b. Why? Explain.                                                                                                             (1)
c. What value did you impart to Almelu?                                                                     (1) Ans:
a.  I would advise Almelu to use smaller quantities of the costlier detergent.
b. Almelo was pouring detergents into the drain. These detergents are not biodegradable. Branched detergents are highly non- degradable because the microbes cannot attack it. Straight chain detergents are being prepared these days to reduce the pollution problem. The costlier detergent contains straight chain hydrocarbon.
c.  The value imparted was to use environmentally friendly substances.

9. Water is a universal solvent. But alcohol also dissolves most of the substances soluble in water. And also many more. Boiling point of water is 100oC and that of alcohol is 80oC. The specific heat of water is much higher than the specific heat of alcohol.
a. List out three possible differences if instead of water as the liquid in our body we had alcohol.                                                                                                             (3)
b. What value can you derive from this special property of water and its innumerable uses in sustaining life on earth?                                                                          (1) Ans:
a.
I. Even a small raise in temperature in the surroundings will raise the temperature of the body because the specific heat of alcohol is much less than the specific heat of water. In order to cool the body more sweating will take place.
II. As there is less H bonding in alcohol it will get evaporated faster. The alcohol will be evaporated at such a fast rate that the liquid has to be ingested always.
III. Ice which floats on water helps aquatic life to exist even in winter as water insulates heat from liquid below it to go back to the surroundings. Solid alcohol does not have such special properties.
b.  Praise is to the almighty that has so thoughtfully given such special properties to water and made it a liquid that could sustain life.

10. After cleaning the refrigerator thoroughly well, Rohit closed it and kept it switched off for two days. After that on opening it, he got a foul smell. His neighbor advised him to keep a piece of charcoal in the fridge.
a.   As a student of chemistry explain why?                                                               (2)
b What value can be drawn from this?                                                                     (1) Ans:
a.  The charcoal piece adsorbs the foul smelling gases.  Eg: in a compost pit large amount of charcoal can be added to remove foul smell.
b.  Help your friends and neighbours.

11.A stain of rust is there on your clothe. You are worried how to remove this stain.
     Shyam tells you to remove this stain using ripened guava.

a. Why?
(2)
b. What is the value Shyam is having when doing this?
(1)
Ans:

a.  The rust is iron oxide. The oxalic acid in guava fruit dissolves iron oxide.
b.  Help your friends and neighbours when you know some simple home techniques instead of chemicals.

12. You are staying near a fertilizer factory. In the middle of the night there is
a leakage of ammonia which is detected by its smell. Within 10 minutes you find the smell is intolerable.



 
.a. What would you do as first aid against this gas spill accident for self and neighbor?                                (2)
b.  What value do you derive from this?                                                                 (1)
Ans:
a.  Ammonia is highly soluble in water. It is detected by its characteristic fishy
odor. Hence keep a wet kerchief on your nose to stop inhaling the gas. Then help your neighbours with your suggestion.
b.  Alertness to tackle disasters for society.

13. Pradeep had very high fever. He was given strong antibiotics. But after recovering from fever he was not able to digest food and was feeling too weak. The grandmother who lived in his neighborhood suggested him to take lots of fruits and vegetables.
a.Why?                                                                                                                     (1)
b.  What is the remedy for this?                                                                                    (1)
c.  What was the value that Pradeep had by taking fruits and vegetables?           (1)
Ans:
a.  Rise in temperature denatures the proteins in our body. The enzymes which are also proteins get denatured. The body has to regenerate these enzymes. Till then Pradeep will continue to feel weak as the enzymes to digest food and for respiration are destroyed due to high temperature and change in pH. Even after the enzymes are regenerated, vitamins which act as prosthetic groups in enzyme action are to be taken from an external source.
b.  By taking fruits and vegetables Pradeep is actually taking in vitamins.
c.  He obeyed an elderly person’s advice.

14. The chairman, Kandla (Gujrat) port due to water scarcity has decided to desalinate sea water to obtain potable water. 
a. As a student of chemistry which method will be suitable to use?          (1) 
b. Discuss the method.                                                                                  (1)
c. What value have you inculcated in using this method?                              (1)
Ans:
a)  Reverse osmosis.
b)  Discussed
c)  Using less energy ie energy conservation
OR
a)  Desalination using evaporation using sun’s energy
b)  Discuss
c)  Using renewable source of energy.

15.  An innovative washer woman while washing a copper miner’s clothes found that sand and similar dirt particle fell to the bottom, while the ore particles stuck to the soapsuds and came to the top. The washer woman discussed this matter with a client who was a chemist.
a.  What is the reason for this observation?                                                       (2)
b.  What value do you get from this episode?                                         (1)
Ans:
a.  The miner’s clothes had particles of CuS / Cu2S on it. This adhered to the froth and came up.
b.  Keen observation can lead to great discoveries.